过渡金属配合物阴离子,Anionic coordination compound of transition metal ions
1)Anionic coordination compound of transition metal ions过渡金属配合物阴离子
2)transition metal complexes过渡金属配合物
1.Research of organic synthesis of 3,5-dibromo salicylaldehyde-serine Schiff base oftransition metal complexes电有机合成3,5-二溴水杨醛缩丝氨酸过渡金属配合物的研究
2.The study on synthesis of the chiral Schiff basetransition metal complexes and their catalytic performance has attracted more attentions due to their applications in the asymmetric epoxidation of olefins.手性席夫碱过渡金属配合物可以高效催化烯烃不对称环氧化反应,因此其合成及催化性能研究一直以来受到广泛的关注。
3.Several newtransition metal complexes of N- (1-phenyl-3-methyl-4-benzal-pyrazol- 5-one)-isonicotinoylhydrazine (PMBP-INTH) are synthesized by the low heating solid-state reaction and the liquid-state reaction, respectively.通过低热固相化学反应与液相化学反应分别合成了 N-( 1 -苯基 -3-甲基 -4-苯亚甲基吡唑啉酮 -5 ) -异烟酰肼 ( PMBP-INTH)的过渡金属配合物 ,通过元素分析 ,红外光谱分析 ,热重 -差热分析及 XRD分析等对所得产物进行了表征 。
英文短句/例句
1.ETHYLENE OLIGOMERIZATION CATALYZED BY TRANSITION METAL COMPLEXES;过渡金属配合物催化乙烯齐聚的研究
2.Synthesis and Characterization of Complexes of Multi-phosphines with Transition Metals含多齿膦配体的过渡金属配合物的合成及表征
3.The Design and Investigation of the Transition Metal Complexes with Biological Activities具有生物活性的过渡金属配合物的设计与研究
4.Syntheses, Structures and Properties of Transition Metal Compounds with Triazole Derivatives as Ligands;三唑类过渡金属配合物的合成、结构和性质表征
5.Syntheses, Characterization and Crystal Structure of a Novel Polypyridine Ligand and Its Transition Metal Complexes;多吡啶过渡金属配合物的合成、结构及性质研究
6.Synthesis and Characterization of Ferroceny1 Amino-alcohols and Their Complexes of Transitional Metals;二茂铁基氨基醇过渡金属配合物的合成与表征
7.Synthesis and Structure of Late Transition Metal Complexes;后过渡金属配合物的合成及其结构的研究
8.Synthesis and Characterization of the Transition Metal Complexes with Pyridine-2, 6-dicarboxylic;吡啶-2，6-二甲酸过渡金属配合物的合成与表征
9.Synthesis and Characteristic of Transition Metal Complexes of Tetraazamacrocyclic Schiff Bases;四氮大环西佛碱过渡金属配合物的合成与表征
10.THE SYNTHESES OF NOVEL OPEN-CHAIN OXAAZACROWN AND THEIR COMPLEXES;新型开链氮氧杂冠醚过渡金属配合物的合成
11.Synthesis, Structure and Magnetic Properties of Transition Metal Complexes过渡金属配合物的合成、结构及磁性研究
12.Syntheses, Structures and Magnetic Properties of Schiff-Base Transition Metal ComplexesSchiff碱类过渡金属配合物的合成、结构及磁性研究
13.Facile Synthesis and Characterization of Three Transition Metal Complexes of Luteolin3种木犀草素过渡金属配合物的合成和表征
14.Synthesis and Characterization of Isatin 3-semicarbazone Transition Metal Complexes靛红-3-缩氨基脲过渡金属配合物的合成与表征
15.Studies on New Types of Dithiolate and Diimine Transition Metal Coordination Compounds;新型二硫纶和二亚胺过渡金属配合物研究
16.Synthesis and Transition Metal Complexes of Bridging Acylhydrazone and Acythiourea Ligands;桥联酰腙和酰基硫脲过渡金属配合物的研究
ano-transition metal compound有机过渡金属化合物
18.Synthesis and Characterization of Novel Transition Metal-Dicarboxylate Coordination Polymers;新型过渡金属—二羧酸配位聚合物的合成与表征
相关短句/例句
transition metal complexes过渡金属配合物
1.Research of organic synthesis of 3,5-dibromo salicylaldehyde-serine Schiff base oftransition metal complexes电有机合成3,5-二溴水杨醛缩丝氨酸过渡金属配合物的研究
2.The study on synthesis of the chiral Schiff basetransition metal complexes and their catalytic performance has attracted more attentions due to their applications in the asymmetric epoxidation of olefins.手性席夫碱过渡金属配合物可以高效催化烯烃不对称环氧化反应,因此其合成及催化性能研究一直以来受到广泛的关注。
3.Several newtransition metal complexes of N- (1-phenyl-3-methyl-4-benzal-pyrazol- 5-one)-isonicotinoylhydrazine (PMBP-INTH) are synthesized by the low heating solid-state reaction and the liquid-state reaction, respectively.通过低热固相化学反应与液相化学反应分别合成了 N-( 1 -苯基 -3-甲基 -4-苯亚甲基吡唑啉酮 -5 ) -异烟酰肼 ( PMBP-INTH)的过渡金属配合物 ,通过元素分析 ,红外光谱分析 ,热重 -差热分析及 XRD分析等对所得产物进行了表征 。
3)transitional metal complex过渡金属配合物
1.Transitional metal complexes of pyromellitic acid were synthesized by homogeneous precipitation method,and characterized by TG,element analysis and FTIR.用均匀沉淀法合成了均苯四甲酸过渡金属配合物。
4)transition metal complex过渡金属配合物
1.Synthesis and property of a new type tripodal Schiff base and itstransition metal complexes新型三脚架结构席夫碱及其过渡金属配合物的合成与性质
2.The cyclodextrin and its derivative inclusion coordination can not only include with guest molecule, but also withtransition metal complexes.环糊精及其衍生物不仅能与简单客体分子包合,也能与过渡金属配合物进行包合的研究。
3.DNA hydrolytic cleavage promoted bytransition metal complexes is also discussed in detail.本文讨论了过渡金属配合物导致ＤＮＡ双链断裂的各种攫氢反应及碱基氧化机理，对由水解过程促进ＤＮＡ断裂的过渡金属配合物也作了介绍。
5)transitional metal complexes过渡金属配合物
1.Synthesis and characterization oftransitional metal complexes of 1,2,3,4-butanetetracarboxylic acid;1,2,3,4-丁烷四羧酸过渡金属配合物的制备和表征
2.Synthesis and characterization oftransitional metal complexes with ferroconyl benzyl hydrazine;二茂铁甲酰基苄基肼过渡金属配合物的合成与表征
6)transition-metal complex过渡金属配合物
1.Recent advance intransition-metal complexes of hydroxamic acid as oxygenase models;异羟肟酸过渡金属配合物仿加氧酶研究进展
2.Synthesis and crystal structure of silicontungstate modified bytransition-metal complexes;由过渡金属配合物修饰的硅钨多金属氧酸盐的合成与晶体结构
3.It is decorated bytransition-metal complex bisupporting Keggin-type molybdenum phosphate under mild hydrothermal conditions and structurally characterized by IR,elemental analyses and single-crystal X-ray diffraction.利用中温水热技术,成功合成了一种新的过渡金属配合物双支撑的Keggin型钼磷杂多金属氧酸盐[Zn(2,2′-bipy)_2]_2[PMo_(11)~ⅥMo~ⅤO_(40)],并采用红外光谱、元素分析、单晶X射线衍射等进行了表征。
延伸阅读
外轨配合物和内轨配合物根据L.C.鲍林的价键理论,具有八面体结构并有4个未成对电子的、顺磁性的[CoF6]3-,或有5个未成对电子的、顺磁性的[Fe(H2O)6]3+,其配位成键杂化轨道为4s4p34d2，所用d 轨道与s和p轨道是属于同一主能级的。这类具有nsnp3nd2形式的配合物(见配位化合物), 因为使用了外层的d轨道,所以叫做外轨配合物。两种配合物的杂化成键轨道分别如图所示。对于具有八面体结构且所有电子都是成对的、抗磁性的[Co(NH3) 6]3+， 或具有1个未成对电子的、 顺磁性的[Fe(CN)6]3-,其成键杂化轨道为3d24s4p3,使用了比s和p轨道低一级主能级层中的d轨道。这类具有(n-1)d2nsnp3型式的配合物,由于使用了内层的d轨道，所以叫做内轨配合物。在四配位体系中，具有四面体结构且有两个未成对电子的顺磁性的[NiCl4] 2-,其成键杂化轨道为4s4p3,属外轨配合物。而所有电子都成对的、抗磁性的[Ni(CN)4]2-，其成键杂化轨道为3d4s4p2,是平面正方形结构，属内轨配合物。两种配合物的杂化成键轨道如图所示。
