手性双卟啉,Chiral bis-porphyrin
1)Chiral bis-porphyrin手性双卟啉
2)Chiral zinc bisporphyrin手性锌双卟啉
3)Chiral porphyrin手性卟啉
1.A new series of chiral binaphthyl compounds 1～9 and rigid chiral porphyrins 14～17 with similar chiral auxiliaries but with different dimensions of chiral pockets were synthesized and characterized by elemental analysis, UV-Vis, MS, IR, 1H NMR and 13C NMR.用1HNMR对其中代表性的联萘化合物6,8和手性卟啉14,16的结构特点进行了讨论。
2.Then,a chiral porphyrin was synthesized by the esterification between the unsymmetric porhyrin and L-BOCphenylalanine.利用四苯基卟啉meso位的可调性合成一种新型不对称卟啉,通过酯键连接叔丁氧羰基(BOC)保护的L-苯丙氨酸(L-BOC-Phen-OH)而使卟啉具有手性识别的能力,并研究了该手性卟啉对L-丙氨酸甲酯和D-丙氨酸甲酯分子识别能力的不同。
3.So,synthesis of new kinds of chiral porphyrins as the catalysts to synthesize organic compounds with high selectively and efficiently in mild condition and explainning its catalysis mechanism is a hot topic.在浓盐酸体系中,用氯化亚锡将其还原成5,10,15,20-四(4-氨基苯基)卟啉,进一步用D-樟脑酮酰氯进行酰化,合成了两种新型手性卟啉:5,10,15,20-四(4-D-樟脑酮酰胺基苯基)卟啉;5,10,15-三(4-D-樟脑酮酰胺基苯基)-20-(4-氨基苯基)卟啉。
4)Chiral zinc porphyrin手性锌卟啉
1.Molecular recognitions of four pairs of amino acid esters by the chiral zinc porphyrin have been investigated with UV Vis spectral method.通过紫外-可见光谱滴定法,研究了手性锌卟啉配合物与四对对映异构的手性氨基酸酯客体在CHCI3中的分子识别行为。
5)achiral porphyrin非手性卟啉
6)Chiral metalloporphyrin手性金属卟啉
英文短句/例句
1.Synthesis and Molecular Recognition of Metalloporphyrins and Porphyrin-Salen Dimers;手性金属卟啉配合物以及卟啉-Salen二聚物的合成及分子识别研究
2.Synthesis and Nonlinear Optical Characterization of a Chiral Metalloporphyrin新型手性金属卟啉的合成及非线性光学性质研究
3.Synthesis of Hydrophilicity Porphyrins and Their Metal Complexes and Their Chemical Simulation;亲水性卟啉及金属卟啉的合成及化学模拟
4.Effect of Solvent on Optical Nonlinear Absorption of Porphyrin and Metalloporphyrins卟啉和金属卟啉光学非线性吸收的溶剂影响
5.Studies on Metalloporphyrins Catalyzed Oxidation Reactions and Asymmetric Catalysis Using Chiral N-Heterocyclic Carbenes;金属卟啉的催化氧化和手性N-杂环卡宾的不对称催化研究
6.Structures and Spectroscopic Properties of Meso-tetrasubstituted Porphyrin and Metal Porphyrin Complexes Based on Density Functional Theory Calculations密度泛函理论研究中位四取代卟啉及金属卟啉的结构与光谱性质
7.Study on Recognition of Biomolecules by Porphyrin and Metalloporphyrin;卟啉及金属卟啉对生物分子识别作用的研究
8.The Research Development of Porphyrins and Metalloporphyrins卟啉及金属卟啉配合物的化学研究进展
9.Study on the Preparation and Catalytic Activity of Carbon Suppored Metalloporphyrins Catalysts;碳载金属卟啉催化剂及其催化性能的研究
10.The Research on Consecutive Experiment of Aerial Oxidation Cyclohexane Catalyzed by Metalloporphyrins;金属卟啉催化氧化环已烷连续性试验研究
11.Investigation on Selective Aerobic Oxidation of p-Xylene Catalyzed by Metalloporphyrins;金属卟啉选择性催化空气氧化对二甲苯的研究
12.Spectroscopy Behavior of Metalloporphyrins and Their Interactions with DNA;金属卟啉的光谱特性及其与DNA相互作用的研究
13.Research Overview of Metalloporphyrin and Their Biomimetic Catalytic Property金属卟啉类化合物的仿生催化性能研究概况
14.Synthesis of the Compounds of Metalloporphyrin and Chlorins-5-Fluorouracil;金属卟啉和二氢卟吩-5-氟尿嘧啶化合物的合成
15.Synthesis of Mentalloporphrin-5-Fluorouracil Compounds with Different Mental Center;金属卟啉5-氟尿嘧啶化合物的合成
16.Rapid determination of organophosphate pestidcides by fluorescence spectrometry of metal porphyrin金属卟啉荧光法快速检测有机磷农药
17.Nonlinear Optical Properties of Semiconductor Nanoparticles and Metalloporphyrin;半导体纳米材料和金属卟啉的非线性光学性质的研究
18.Spectral Characterization of the Interaction of Porphyrin and Metalloporphyrin with Biomacromolecule;卟啉及金属卟啉与生物大分子相互作用的光谱表征
相关短句/例句
Chiral zinc bisporphyrin手性锌双卟啉
3)Chiral porphyrin手性卟啉
1.A new series of chiral binaphthyl compounds 1～9 and rigid chiral porphyrins 14～17 with similar chiral auxiliaries but with different dimensions of chiral pockets were synthesized and characterized by elemental analysis, UV-Vis, MS, IR, 1H NMR and 13C NMR.用1HNMR对其中代表性的联萘化合物6,8和手性卟啉14,16的结构特点进行了讨论。
2.Then,a chiral porphyrin was synthesized by the esterification between the unsymmetric porhyrin and L-BOCphenylalanine.利用四苯基卟啉meso位的可调性合成一种新型不对称卟啉,通过酯键连接叔丁氧羰基(BOC)保护的L-苯丙氨酸(L-BOC-Phen-OH)而使卟啉具有手性识别的能力,并研究了该手性卟啉对L-丙氨酸甲酯和D-丙氨酸甲酯分子识别能力的不同。
3.So,synthesis of new kinds of chiral porphyrins as the catalysts to synthesize organic compounds with high selectively and efficiently in mild condition and explainning its catalysis mechanism is a hot topic.在浓盐酸体系中,用氯化亚锡将其还原成5,10,15,20-四(4-氨基苯基)卟啉,进一步用D-樟脑酮酰氯进行酰化,合成了两种新型手性卟啉:5,10,15,20-四(4-D-樟脑酮酰胺基苯基)卟啉;5,10,15-三(4-D-樟脑酮酰胺基苯基)-20-(4-氨基苯基)卟啉。
4)Chiral zinc porphyrin手性锌卟啉
1.Molecular recognitions of four pairs of amino acid esters by the chiral zinc porphyrin have been investigated with UV Vis spectral method.通过紫外-可见光谱滴定法,研究了手性锌卟啉配合物与四对对映异构的手性氨基酸酯客体在CHCI3中的分子识别行为。
5)achiral porphyrin非手性卟啉
6)Chiral metalloporphyrin手性金属卟啉
延伸阅读
红细胞生成性血卟啉病红细胞生成性血卟啉病属于血卟啉病的一种类型。系骨髓内卟啉代谢紊乱所致，故又称"骨髓性血卟啉病"。临床罕见，仅见于小儿，与遗传有关。临床分三型，即尿卟啉型、粪卟啉型及原卟啉型。其中以原卟啉型较常见，属常染色体显性遗传，其遗传基因有量变的外显率，可能与抑制基因和环境因素有关，一般认为红细胞的原卟啉来源于骨髓，血浆中的原卟啉则来源于肝脏及含有原卟啉的红细胞破坏。童年发病，病情较轻，主要表现为光感性皮肤损害，暴露处皮肤有痛、痒、红、肿、尤以面部、手背、指关节伸面为著，偶有轻度溶血性黄疸，周围血网织红细胞增多，骨髓呈幼红细胞增生现象，因含有大量卟啉，故可见红色荧光。血中也有荧光红细胞所见。尿、粪中，尿卟啉、粪卟啉增多。此外，尿胆元常增加。采取对症治疗皮肤损害和溶血性贫血，并预防复发，β胡萝卜素对本病有较好疗效。
