双核配合物,binuclear complex
1)binuclear complex双核配合物
1.Thebinuclear complex [Cu 2(TS)(H 2O)]·H 2O, where TS donates the binuclearing ligand derived from the schiff base N,N"_bis(3_carboxylsalicylidene)trimethylenediamine, was obtained through the selfdecomposition of mononuclear complex Na 2CuTS·H 2O in the methanol/water.利用单核配合物Na2 CuTS·H2 O在溶剂中的不稳定性质 ,自分解并重新组装得到了双核配合物 [Cu2 (TS)(H2 O) ]·H2 O 。
2.A synthetic method of LnH2salen complexes was described and a series ofbinuclear complexes were obtained.合成了稀土Ｎ，Ｎ－亚乙基双（水杨醛缩亚胺）（Ｈ２ｓａｌｅｎ）双核配合物，通过元素分析、热分析、紫外、红外、远红外光谱、磁化率及１Ｈ、１３ＣＮＭＲ谱与Ｔ１的测定，确定了他们与前人合成的配合物有所不同，其化学组成为［Ｌｎ２（Ｈ２ｓａｌｅｎ）３（ＮＯ３）４］（ＮＯ３）２·３Ｈ２Ｏ（Ｌｎ＝Ｌａ，Ｐｒ，Ｎｄ，Ｓｍ，Ｇｄ，Ｔｂ，Ｅｒ，Ｙｂ及Ｙ），并对它们的配位作用、波谱及可能应用进行了探讨。
3.Six new binary complexes Cr(L-A)3[L=H, 2-OCH3, 4-OCH2CH3; A=2-(COO)C6H4CONHC6H4-,COOCH2CH2CONHC6H4-]and four newbinuclear complexes Cr(L-A)3?/2CuX2[L=2-OCH3 , 4-OCH2CH3 : X=C1 , Br] were synthesized and characterized by elemental analysis, infrared and ultraviolet spectra as well as molar conductors.本文报道了六种二元配合物Cr（L-A）_3[L=H，2-OCH_3，4-OCH_2CH_3；A=2-（COO）C_6H_4CONHC_6H_4-，COOCH_2CH_2CONHC_6H_4-]和四种双核配合物Cr（L-A）_3·3/2CuX_2[其中L=2-OCH_3，4-OCH_2CH_3；X=Cl，Br]的合成。
英文短句/例句
1.SYNTHESIS AND CHARACTERIZATION OF Eu(Ⅲ)-Zn(Ⅱ) BINUCLEAR COMPLEXES铕(Ⅲ)-锌(Ⅱ)双核配合物的合成和表征
2.Ab Initio Study on Cu(Ⅱ)-VO(Ⅱ) Heterobinuclear Complex;Cu(Ⅱ)-VO(Ⅱ)异双核配合物的从头算研究
3.Synthesis and Characterization of Triethylene-tetramine Schiff-base Cu(Ⅱ) Dinuclear Complex;三乙烯四胺Schiff碱Cu(Ⅱ)双核配合物的合成与表征
4.SYNTHESIS AND CHARACTERIZATION OF COPPER(Ⅱ) -EUROPIUM(Ⅲ) HETROBINUCLEAR COMPLEXES;铜(Ⅱ)-铕(Ⅲ)杂双核配合物的合成与性质研究
5.The Self|assembly of One Dimensional Chain Complex of Bridged Binuclear Copper(II)一维链状桥联双核铜配合物的自组装
6.Oxidative DNA Cleavage Promoted by Binuclear Copper Complexes双核铜配合物对DNA的氧化切割活性
7.Theoretical study on mononuclear and binuclear cobalt carbonyl nitrosyls单核和双核钴羰基-亚硝基配合物的理论研究
8.SYNTHESIS AND CRYSTAL STRUCTURES OFMONONUCLEAR,CONJUGATED MONONUCLEAR ANDBINUCLEAR COPPER(Ⅱ)-SCHIFF BASE COMPLEXES;单核、共轭单核、双核Schiff碱铜配合物的合成及晶体结构(英文)
9.Synthesis and Characterization of Binuclear Complexes and Their Catalytic Activitity Research;双核金属配合物的合成、表征及其仿生催化研究
10.Synthesis of a novel μ-terephthalato binuclear copper(II) complexes;对苯二甲酸根桥联双核铜(Ⅱ)配合物的合成
11.A Novel Bicopper(Ⅱ) Chain Complex Containing NO_2~- as Bridging Ligand: Synthesis and Magnetism;亚硝酸根桥联双核铜(Ⅱ)配合物的合成与磁性
12.Synthesis,Crystal Structure and Magnetic Properties of Chloro-bridged Binuclear Mn (Ⅱ)Complex氯桥联双核Mn(Ⅱ)配合物的合成、结构与磁性
13.An Electrochemical Study on Binuclear Big Bird Complexes of Ni( Ⅱ ) and Cu( Ⅱ )镍(Ⅱ)和铜(Ⅱ)的双核大鸟配合物的电化学研究
14.Preliminary Study on Asymmetric Reactions Catalyzed by Chiral Binuclear Metallic Complex;手性双核金属配合物催化的不对称反应初探
15.IR 、TG-DTG Analysis Investigation of a New Dinuclear Complex Containing Copper(II)and Taurine;牛磺酸双核铜配合物的红外及热分解机理分析
16.Theoretical Studies on the Binuclear Homoleptic Rhodium Carbonyls双核多羰基铑金属配位化合物的理论研究
17.Process for Preparing Binuclear Manganese(Ⅳ) Complex via Acetylsalicylic Acid乙酰水杨酸制备双核水杨酸锰(Ⅳ)配合物
18.Effects of binuclear metal phthalocyanine compounds to Li/SOCl_2 battery双核金属酞菁配合物对Li/SOCl_2电池的影响
相关短句/例句
dinuclear complex双核配合物
1.Studies on the Spectra of Rare Earth Dinuclear Complexes with o-Phenanthroline Hydrate;稀土邻菲咯啉双核配合物的光谱研究
2.By using a tricyanometalate precursor TpFeⅢ(CN)3- (Tp=hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridgeddinuclear complex, (Tp)FeⅢ(CN)3CuⅡ(bpy)2ClO4·CH3OH (1) (bpy=2, 2′-bipyridine), has been prepared and characterized.采用[TpFeⅢ(CN)3]-作为构筑基块,合成并表征了一个氰基桥联双核配合物[(Tp)FeⅢ(CN)3CuⅡ(bpy)2]ClO·4CH3OH(1)。
3.Thedinuclear complex[Pb(η2-o-FcCOC6H4COO)(μ2-η2-o-FcCOC6H4COO)(phen)]2·CH3OH is prepared with Pb(OAc)2·3H2O,o-ferrocecarbonyl benzoic sodium(o-FcCOC6H4COONa,Fc=(η5-C5H5)Fe(η5-C5H4))and 1,10-phenanthroline(phen) as materials in the mixing solvent of methanol and ethanol.3H2O与邻羧基苯甲酰二茂铁钠盐[o-FcCOC6H4COONa,Fc=(η5-C5H5)Fe(η5-C5H4)]和1,10-邻菲啰啉(phen)在甲醇和乙醇的混合溶剂中反应,合成了一个双核配合物[Pb(η2-o-FcCOC6H4COO)(μ2-η2-o-FcCOC6H4COO)(phen)]2。
3)dinuclear complexes双核配合物
1.Advances in the artificial hydrolysis enzyme models ofdinuclear complexes developed in resent years are reviewed.本文综述了近年来双核配合物作为人工酶的研究进展 ,讨论了这类配合物的催化水解机理及影响因
4)Binuclear complexes双核配合物
5)two-dinuclear copper complex双双核铜配合物
6)binuclear copper(Ⅱ) complex双核铜配合物
1.Synthesis and crystal structure of a novel bis(phenoxo) bridged binuclear copper(Ⅱ) complex;双酚氧桥联双核铜配合物的合成与晶体结构
延伸阅读
外轨配合物和内轨配合物根据L.C.鲍林的价键理论,具有八面体结构并有4个未成对电子的、顺磁性的[CoF6]3-,或有5个未成对电子的、顺磁性的[Fe(H2O)6]3+,其配位成键杂化轨道为4s4p34d2，所用d 轨道与s和p轨道是属于同一主能级的。这类具有nsnp3nd2形式的配合物(见配位化合物), 因为使用了外层的d轨道,所以叫做外轨配合物。两种配合物的杂化成键轨道分别如图所示。对于具有八面体结构且所有电子都是成对的、抗磁性的[Co(NH3) 6]3+， 或具有1个未成对电子的、 顺磁性的[Fe(CN)6]3-,其成键杂化轨道为3d24s4p3,使用了比s和p轨道低一级主能级层中的d轨道。这类具有(n-1)d2nsnp3型式的配合物,由于使用了内层的d轨道，所以叫做内轨配合物。在四配位体系中，具有四面体结构且有两个未成对电子的顺磁性的[NiCl4] 2-,其成键杂化轨道为4s4p3,属外轨配合物。而所有电子都成对的、抗磁性的[Ni(CN)4]2-，其成键杂化轨道为3d4s4p2,是平面正方形结构，属内轨配合物。两种配合物的杂化成键轨道如图所示。
